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Wine
is potent stuff. Not so much for its alcohol content as for its cultural
significance. It's romantic. It's holy. It's a symbol
of human achievement. It takes a lot of care to make and keep it, from
planting the vine to pulling the cork.
The cork is drenched in tradition, too. At the high end of the wine trade,
nothing will serve but cork off the tree. Forget about a twist-off cap.
A company in Kent, Wash., hopes to change that attitude. The company,
Supreme Corq, says it has something more reliable, a closure made of a
proprietary blend of polymers.
Ana Hueto, a chemical engineer in product development at Supreme Corq,
said that the product is injection molded of a foamed material and has
an even cell structure. She said the manufactured closures are more consistent
in performance than cork produced by the randomness of nature. The company
is studying ways to offer closures specifically adapted to different types
of wine.
Plastic closures of this type are being used to protect many commercial
wines, but so far none of the company's products are used to bottle
fine varietals.
One of the big questions about a closure, natural or not, is how much
oxygen it lets seep into the bottle. Too much over time can cause wine
to spoil.
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| Lab manager Rebecca Ortiz with
the banks of samples; plastic closures are made by Supreme Corq. |
To test its closures for permeability, Supreme Corq sends them to Impact
Analytical in Midland, Mich. Rebecca Ortiz, manager of Impact Analytical's
barrier properties laboratory, has designed a special setup to speed tests
of artificial corks.
Her tests monitor the permeability of a closure until its oxygen transmission
rate reaches a steady state. From start to finish, that takes 30 days
or more.
She has eight Ox-Tran Model 2/21 testing machines, from Mocon in Minneapolis.
According to Mocon, the system uses a coulometric sensor that is able
to detect traces of oxygen down to parts per billion.
It is a chemical cell that generates an electrical current when it is
exposed to oxygen. It uses a reaction that takes place between a cadmium
anode and a graphite cathode.
A sample closure fits into a bottleneck that is then attached to a board.
Ortiz said that tubing and Swagelok fittings allow inert gas to flush
trapped air from the enclosed space and also take samples to the sensor.
Once in the bottle, only a small portion of the closure's surface
remains exposed to the air. Before it enters the bottle, though, the artificial
cork has been sitting in the atmosphere and is saturated with oxygen.
It takes a few days for that oxygen to dissipate.
The Ox-Tran can switch back and forth between two gas streams, so it could
take the eight machines more than a month to test 16 samples. To speed
things up, Ortiz designed a setup in which there are two banks of 12 samples
each. Now, one machine handles 24 samples.
When the samples are ready, Ortiz turns valves to connect one sample from
each bank to the testing machine. They stay hooked up to the Ox-Tran all
day long. The machine receives air samples from the first bank's
sample for a while, then switches to the second bank. It repeats, bank
A and then B again. After that, the machine resets itself.
The complete cycle repeats five times in 24 hours. Every day, Ortiz manually
switches to the next set of samples, so each sample is tested every 12
days.
The manual switching was a matter of cost. So was building the tables
in-house. She put it up for proposals, but "the job bid was too
high," she said.
The usual pattern for the tests is to start with high readings of oxygen
that come down and eventually stabilize. How much oxygen finally gets
through?
She said oxygen transfer is minimal, requiring the sensitivity of the
Mocon device. Small wonder you have to let your cabernet breathe.
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